Issue:
I want to have external emails coming in to userX@domain.com go to userY@domain.com. Can this be done in proofpoint?
Answer:
No. Assuming you're on Office365 (80%+ of our clients are), you need to do that in office365 with a mail flow rule.
Solution:
Go to your exchange admin
-> Mail Flow
---> RULES
Create a new rule as per below: